\(n_{H_2S}=\dfrac{0.672}{22.4}=0.03\left(mol\right)\)

\(a.\)

\(n_{NaOH}=0.75\cdot0.1=0.075\left(mol\right)\)

\(T=\dfrac{0.075}{0.03}=2.5>2\)

=> Tạo muối trung hòa

\(2NaOH+H_2S\rightarrow Na_2S+H_2O\)

\(0.06............0.03.........0.03\)

\(m_{Na_2S}=0.03\cdot78=2.34\left(g\right)\)

\(b.\)

\(n_{NaOH}=0.42\cdot0.1=0.042\left(mol\right)\)

\(T=\dfrac{0.042}{0.03}=1.4\)

=> Tạo 2 muối

\(n_{Na_2S}=a\left(mol\right),n_{NaHS}=b\left(mol\right)\)

\(\left\{{}\begin{matrix}2a+b=0.042\\a+b=0.03\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}a=0.012\\b=0.018\end{matrix}\right.\)

\(m_{Muối}=0.012\cdot78+0.018\cdot56=1.944\left(g\right)\)

\(n_{Na_2S}=n_{NaHS}=a\left(mol\right)\)

\(n_{NaOH}=2a+a=3a=0.03\left(mol\right)\)

\(\Rightarrow a=0.01\)

\(V=\left(0.01+0.01\right)\cdot22.4=0.448\left(l\right)\)

TH2 : NaOH dư 

\(n_{NaOH\left(dư\right)}=n_{Na_2S}=a\left(mol\right)\)

\(2NaOH+H_2S\rightarrow Na_2S+2H_2O\)

\(2a........a.........a\)

\(n_{NaOH\left(dư\right)}=0.03-2a=a\left(mol\right)\)

\(\Rightarrow a=0.03\)

\(V=0.672\left(l\right)\)

nNaOH= 0,03(mol)

PTHH: 2 NaOH + H2S -> Na2S +  + 2 H2O

2x_____________x_____x(mol)

NaOH + H2S -> NaHS + H2O

x________x_____x(mol)

nNa2S=nNaHS=x(mol)

2x+x=0,03 <=>x=0,01

=> V(H2S,đktc)=2x.22,4=0,448(l)= 448(ml)

Chúc em học tốt!

Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=\dfrac{5,04}{22,4}=0,225\left(mol\right)\\n_{NaOH}=0,25\cdot1,75=0,4375\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Tạo 2 muối

PTHH: \(CO_2+NaOH\rightarrow NaHCO_3\)

              a______a________a           (mol)

            \(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)

              b______2b________b          (mol)

Ta lập được HPT \(\left\{{}\begin{matrix}a+b=0,225\\a+2b=0,4375\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,0125\\b=0,2125\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{NaHCO_3}=0,0125\cdot84=1,05\left(g\right)\\m_{Na_2CO_3}=0,2125\cdot106=22,525\left(g\right)\end{matrix}\right.\)

\(n_{CO_2}=\dfrac{5,04}{22,4}=0,225\left(mol\right);n_{NaOH}=1,75\cdot0,25=0,4375\left(mol\right)\)

Ta có : \(\dfrac{n_{NaOH}}{n_{CO_2}}\approx1,9\)

=> Tạo cả hai muối trung hoà và axit, CO2 và NaOH đều pư hết.

PTHH:

\(CO2+2NaOH->Na2CO3+H2O\)

x             2x                   x       

\(CO2+NaOH->NaHCO3\)

y              y                  y

Theo đề ta có:

\(n_{CO2}=x+y=0,225\left(mol\right);n_{NaOH}=2x+y=0,4375\left(mol\right)\)

Giải hệ : x= 0,2125mol; y = 0,0125mol

Muối tan trong ddX là Na2CO3 và NaHCO3

\(m_{tan}=0,2125\cdot\left(23\cdot2+12+16\cdot3\right)+0,0125\cdot\left(23+1+12+16\cdot3\right)\\ =23,575\left(g\right)\)

\(n_{H_2S}=\dfrac{0.448}{22.4}=0.02\left(mol\right)\)

\(n_{NaOH}=0.1\cdot0.5=0.05\left(mol\right)\)

\(T=\dfrac{0.05}{0.02}=2.5>2\)

\(2NaOH+H_2S\rightarrow Na_2S+H_2O\)

\(0.04........0.02..............0.02\)

\(n_{Na_2S}=0.02\left(mol\right)\)

\(n_{NaOH\left(dư\right)}=0.05-0.04=0.01\left(mol\right)\)

\(n_{NaOH}=0.24\cdot0.1=0.024\left(mol\right)\)

\(T=\dfrac{0.024}{0.02}=1.2\)

=> Tạo 2 muối

\(n_{Na_2S}=a\left(mol\right),n_{NaHS}=b\left(mol\right)\)

\(\left\{{}\begin{matrix}2a+b=0.024\\a+b=0.02\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}a=0.004\\b=0.016\end{matrix}\right.\)

\(n_{SO_2} = \dfrac{4,48}{22,4} = 0,2(mol) ; n_{NaOH} = 0,25(mol)\\ 1<\dfrac{n_{NaOH}}{n_{SO_2}} = \dfrac{0,25}{0,2} = 1,25 <2 \to Muối\ tạo\ thành : NaHSO_3(a\ mol) ; Na_2SO_3(b\ mol)\\ n_{SO_2} = a + b = 0,2(mol)\\ n_{NaOH} = a + 2b = 0,25(mol)\\ \Rightarrow a = 0,15 ; b = 0,05\\ m_{NaHSO_3} = 0,15.104 = 15,6(gam) \\ m_{Na_2SO_3} = 0,05.126 = 6,3(gam)\)